I would say that the best way to leave the solder out of the signal path is to use tight mechanical connections first, then solder the joint. The electrons will take the path of least resistance, which would be the copper, or tin plating. The RohS solder leave out the lead and add copper, which should make them better conductors, but melt at a higher temp. adding to the working difficulty.
Electrical resistivity and conductivity - Wikipedia, the free encyclopedia
Solder - Wikipedia, the free encyclopedia
Electrical resistivity and conductivity - Wikipedia, the free encyclopedia
Solder - Wikipedia, the free encyclopedia
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