I agree that tubes don't "filter" in the frequency domain. However, due to their non-linearities, they can generate new frequencies that weren't originally in the signal. A tube that clips sharply, generating a lot of high-order harmonics, will sound brighter than one with a more gradual clipping characteristic.
And these characteristics depend on fine details of manufacturing (like the uniformity of spacing of the control grid wires) that aren't too well specified or controlled.
And these characteristics depend on fine details of manufacturing (like the uniformity of spacing of the control grid wires) that aren't too well specified or controlled.
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